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العنوان
Synergistic Effects of Sonolysis and
Photocatalysis in Degradation of Some
Nitroaromatic Compounds in Industrial
Wastewater /
المؤلف
Moawad,Ahmed Ezzat Taha.
هيئة الاعداد
باحث / Ahmed Ezzat Taha Moawad
مشرف / Nabawaya A. Moussa
مشرف / Christine A. Philip
مشرف / Ahmed M. Al-Sabagh
مشرف / Fatma Z.M. Yehia
تاريخ النشر
2018
عدد الصفحات
235p.:
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
الكيمياء
تاريخ الإجازة
1/1/2018
مكان الإجازة
جامعة عين شمس - كلية العلوم - الكيمياء
الفهرس
Only 14 pages are availabe for public view

from 235

from 235

Abstract

Metal oxychlorides of Fe, Cu, Bi and Zn were
prepared and tested in heterogeneous Fenton
degradation of 20 ppm of 2-nitrophenol or nitrobenzene
in the presence of ultrasonic (US, 20 kHz), ultraviolet
(UV, 6 W), and US/UV coupled irradiations. The
different experimental conditions including the catalysts
dosages, hydrogen peroxide concentration, pH value,
temperature, pollutant concentration and irradiation time
were optimized and the reusability of the tested metal
oxychlorides was investigated as well. The degradation
capability of 2-NP or NB follows the order US/UV> UV
> US. The rate constant of degradation using
sonophotocatalytic system was even higher than the sum
of rates of individual systems due to its synergistic
performance. The rate constant of degradation followed
the same order of mentioned metals oxychloride. The
mechanism proposed considers a major role of produced
hydroxyl radicals while the difference in band gap
energy was emphasized in case of Bi and Zn
oxychlorides.