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العنوان
The effect of cation exchange on electronic Structure and physical properties
of titanate nanotubes /
المؤلف
Nsr, Hager Samir Gad.
هيئة الاعداد
باحث / هاجر سمير جاد نصر
مشرف / ايمن حسن ذكى
مشرف / محمد طه
الموضوع
Nanotubes. Titanates.
تاريخ النشر
2022.
عدد الصفحات
96 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الفيزياء النووية والطاقة العالية
الناشر
تاريخ الإجازة
24/7/2022
مكان الإجازة
جامعة بني سويف - كلية الدراسات العليا للعلوم المتقدمة - علوم المواد وتكنولوجيا النانو
الفهرس
Only 14 pages are availabe for public view

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Abstract

Sodium titanate nanotubes (Na-TNTs) and their metal-doped derivatives were prepared using simple hydrothermal and metal ion exchange methods, respectively. The as-prepared and doped materials were characterized by X-ray powder diffraction, thermal gravimetric analysis, high-resolution transmission electron microscopy, field-emission scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The dielectric constant, the loss tangent, and the AC electrical conductivity of NaM-TNTs (where M = Cr, Cu, Ni, or Zn) were measured at selected frequencies (400 kHz and 2 MHz) as a function of temperature. The activation energy was calculated and reported at 400 kHz. All samples showed mixed ionic electronic conductivity. Some of the materials were used as examples for theoretically exploring structures and optoelectronic properties (band structures, density of states, reflectivity, absorption curve, refractive index, dielectric function, optical conductivity, and loss function) using density functional theory calculations. The band gaps of the studied materials were found to vary from 2.4 to 3.17 eV, which makes them suitable for many optoelectronic applications.