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Abstract The citrate sol-gel process used for preparation of modified M/Ni Zn Fe2O4 (M = Al, Ce, Sm, and Zr) nanostructures and calcined at 800oC for 3h, in the air. The sol-gel process was used because of its potential for making fine, high purity and homogeneous powders. Sol-gel is a facial chemical method that has the possibility of preparing a reproducible material in nanoscale and the advantage of the calcination of reducing the total processing time and the calcination temperature. At this study it was added some cations through Ni0.5Zn0.5Fe2O4 such as Al2O3, Ce2O3, Sm2O3, Zr2O4 as the formula AlxNi0.5-xZn0.5Fe2O4 , where (x = 0.0, 0.1, 0.2, 0.3), CexNi0.5Zn0.5-x Fe2O4 , where (x = 0, 0.1,0.2,0.3), SmxNi0.5Zn0.5- xFe2O4 , where (x = 0, 0.2, 0.4, 0.5) and Sm0.4-XZrXNi0.5Zn0.1Fe2O4 ,where (x= 0.2,0.3), to study their effective structural, phase purity and magnetic properties. Prepared nano-sized pure and doped Ni0.5Zn0.5Fe2O4 were characterized by X-ray diffraction to investigate the crystalline phase and morphological characterization analyses, High-resolution transmission electron microscopy and scanning electron microscopy to confirm the formation of Ni-Zn ferrite nanoparticle and estimate the particle sizes, Fourier transforms infrared spectroscopy ensures the characteristic absorption bands of ferrites, investigate and confirmed the formation of spinel structure and Vibrating sample magnetometer to investigate the magnetic induction of the asprepared sample. X-ray diffraction for pure and doped Ni0.5Zn0.5Fe2O4 nano-structure confirms the formation of single phase cubic structure. The estimated crystallite sizes are changes from 27– 31 nm for the prepared nanomagnetic. SEM and HRTEM results revealed that pure and doped Ni0.5Zn0.5Fe2O4 nanocrystalline appeared some aggregate nanostructure with spherical shapes with average size ~29 nm. Infrared absorption spectroscopy shows the spinel ferrite two absorption bands corresponding to the tetrahedral and octahedral sites, which are the significant bands of -Fe2O4 groups, which is due to the formation of Ni0.5Zn0.5Fe2O4 nano-structure. The saturation magnetization (Ms) and coercivity (Hc) values were 47.894 and 70.37 G; for pure Ni0.5Zn0.5Fe2O4 nanocrystalline. The values of both saturation magnetization (Ms) and coercivity (Hc) for the doped samples were varying according to the type and concentration of the dopants. |