الفهرس 
INTRODUCTIONOnly 14 pages are availabe for public view
 |  | from | 231 |  |  |
| | | from | 231 | | |
Abstract
Sulpha drug compounds have received considerable attention in the last decade which plays a central role as chelating agents for a large numbers of metal ions, as they form a stable six-membered ring after complexation with a metal ion. The present study involves preparation of a novel series of transition metal complexes of Cu(II), Co(II), Ni(II), Mn(II) and Cd(II) were synthesized from sulpha drug (N-[4-(5-methyl-isoxazol-3-ylsulfamoyl)-phenyl]-acrylamide (HL)) derived from amidation of 4-amino-N-(5-methyl-isoxazol-3-yl)-benzenesulfonamide with acryloyl chloride in dry benzene as solvent. M(II) complexes of sulpha drug (N-[4-(5-methyl-isoxazol-3-ylsulfamoyl)-phenyl]-acrylamide (HL)) have been synthesized and characterized by elemental analysis, mass spectroscopy, X-ray, IR, 1H NMR, electronic spectra, molar conductance magnetic susceptibility and thermogravimetric studies.
Chapter 1, contains a literature survey includes the importance and structural chemistry of sulpha drug compounds and their different complexes. Chapter 2, involves materials used and the preparation of (N-[4-(5-methyl-isoxazol-3-ylsulfamoyl)-phenyl]-acrylamide (HL)) monemer derived from amidation of 4-amino-N-(5-methyl-isoxazol-3-yl)-benzenesulfonamide with acryloyl chloride in dry benzene as solvent as well as its Cu(II), Co(II), Ni(II), Mn(II) and Cd(II) polymer complexes as well as analytical techniques. Chapters 3, 4 and 5 include on the results and discussion abstracted from this study.