الفهرس | Only 14 pages are availabe for public view |
Abstract The present study gives reasons of the fouling of anion exchange resin which leads to reducing the capacity of resin and treated water quality which cause corrosion in a boiler and turbine and affect electric production in two of electric power plant in Egypt Shoubra El-Khiema and Damietta. The physicochemical results of two electric power plants inlet River Nile water, filtered water and outlet water of ion exchange resins revealed that, total organic carbon (TOC) showed low decreased in filtered water (after treatment) than inlet River Nile water and also TOC was found in the outlet water of an anion exchange resin. Also, fouling of organic matter appeared in used anion resin at two electric power plants, so the problem of anion resin fouling is matched with quantity of TOC in River Nile and filtered water. Sodium Na+ increased in River Nile than permissible limits at two plants but total dissolved solid (TDS) increased than permissible limits only at Damietta River Nile water. Sulphate SO4-2 increased than permissible limits in two plants filtered water but Sodium Na+ increased than permissible limits only at Damietta filtered water. The bacteriological results showed high levels of total coliform (TC), fecal coliform (FC),fecal streptococci (FS) and Pseudomonas aeruginosa in inlet River Nile during summer at two plants and increased of TC in River Nile than permissible limits according to law 48/1982 at Shoubra El-Khiema during spring and summer. The results showed, high levels of bacterial indicators and heterotrophic plate count (HPC) in River Nile and decreased in filtered water at two plants. The mean of electric conductivity of outlet water of mixed bed increased than permissible limits of two plants. New (storage) and used anion resins were contaminated with microorganisms. All bacteria isolated from two plants anion resin were gram positive. Epifluorescence and scan electron microscope (SEM) photomicrographs of the fouled resin beads clearly show microbial fouling by bacteria and viable and dead microbial biofilm. Three isolates of bacteria from Shoubra El-Khiema anion resin were identified that were two of Bacillus sp. and Brevebacterium sp. and two isolates of fungal species which were Penicillium sp. and Fusarium sp. While in Damietta anion resin five isolates of bacteria were identified that were Bacillus spp. and four fungal species which were microscopically identified as Aspergillus flavus, Aspergillus niger, Alternaria sp. and Penicillium sp. Shoubra El-Khiema and Damietta anion exchange resins were fouling by microbial, organic matter and iron leading to decline of the total exchange capacity of anion resin but it still within the acceptable limits at Shoubra El-Khiema but lower than acceptable limits at Damietta electric power plant. Key Words: River Nile, filtered water, ion exchange resin, physicochemical & bacteriological parameters. |