Search In this Thesis
   Search In this Thesis  
العنوان
Factors Affecting the Condensation of Unsaturated Carbonyl Compounds with
Different Amines
الناشر
Women
For Arts, Science and Education/Chemistry
المؤلف
Fatehia lbrahim Abd El-Monem
هيئة الاعداد
باحث / Fatehia lbrahim Abd El-Monem
مشرف / Afaf M. El-Toukhy
مشرف / Shadia M. Abdallah
مشرف / hra M. Awad
مشرف / Halima A. Hefny
تاريخ النشر
2005
عدد الصفحات
201
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
Organic Chemistry
تاريخ الإجازة
1/1/2005
مكان الإجازة
جامعة عين شمس - كلية البنات - Chemistry
الفهرس
Only 14 pages are availabe for public view

from 153

from 153

Abstract

ABSTRACT

Microwave irradiation of a mixture from 3-carboxy-4-[phenyl- or (4-methoxyphenyl)]-3-butenoic acid (2a or b), 2-[phenyl- or (4-methoxyphenyl)]methylenebutanedioic anhydride (3a or b) or methyl 3-carboxy-4-[phenyl- or (4-methoxyphenyl)-]-3-butenoate (4a or b) with different hydrazines, aliphatic or aromatic amines in 1000 watt-microwave oven at 30-80% of its power for 2-20 minutes gives 1,2-bis(3-carboxy-4-phenyl-3-butenoyl)hydrazine (8), 2-(4-methoxyphenyl)methylenebutane- dioic hydarzide (9), N-substituted-3-carboxy-4-aryl-3-buten- amides (5, 12-16, 18, 20, 22, 24, 26, 28, 30, 32 and 34), N-substituted-2-arylmethylenebutanimides (6, 7, 10, 11, 13, 17, 19, 21, 23, 25, 27, 29, 31, 33 and 35) in excellent yields and high purity.
The structures were assigned in accordance to their elemental analysis and spectral data; IR, 1HNMR and MS.