Search In this Thesis
   Search In this Thesis  
العنوان
ELECTROCHEMICAL BEHAVIOUR OF COPPER IN SOME AQUEOUS SOLUTIONS
الناشر
Univesity
المؤلف
Kandil, Al Hussein Bakr Mohammed
هيئة الاعداد
مناقش / Al hussien bakr mohamed kandil
مشرف / A.S. Fouda
مشرف / A. Abd El-Aal
مشرف / A. Abd El-Aal
الموضوع
ELECTROCHEMICAL BEHAVIOUR OF COPPER AQUEOUS SOLUTIONS
تاريخ النشر
2004
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء
الناشر
Univesity
تاريخ الإجازة
1/1/2004
مكان الإجازة
جامعة الزقازيق - كلية العلوم - كيمياء
الفهرس
Only 14 pages are availabe for public view

from 511

from 511

Abstract

The present work is assigned to study the corrosion of copper in 2M nitric acid solution and the inhibiting effect of some phthalimide and glycine derivatives by the weight loss and galvanostatic polarization techniques.
The obtained results showed that the inhibition efficiency of these compounds increased by increasing their concentrations and decreased by raising the temperature, so that the adsorption of these compounds is physically adsorped on the copper surface.
Temkin’s adsorption isotherm fits the experimental data for the studied compounds so that some thermodynamic parameters for adsorption of these compounds were calculated.
The effect of temperature on the corrosion rate was studied using weight loss method at temperature range 303 – 318 K. The results revealed that by increasing the temperature, the rate of corrosion is increased. Linear Arrhenius plots were obtained in the absence and presence of these compounds. From the slopes of these lines, the activation energies were calculated and some thermodynamic parameters for the activation process were computed.
The mechanism of the inhibition process was determined using the polarization technique. The measured Tafel slopes indicate that these compounds act as a mixed type inhibitors but cathode is more polarized when an external current was applied.
The results were explained on the basis of the molecular structure and the substituent groups and their charge densities.