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العنوان
The structural properties and catalytic activity of some mixed oxide catalysts /
المؤلف
Mohammady, Ayman Mohammed.
هيئة الاعداد
باحث / أيمن محمد محمدى
مشرف / السيد عبدالعظيم الشرقاوي
مشرف / عوض ابراهيم أحمد
مشرف / شوقي محمد حسن
الموضوع
Chemistry. Oxides.
تاريخ النشر
2004.
عدد الصفحات
152 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الكيمياء الحيوية ، علم الوراثة والبيولوجيا الجزيئية
تاريخ الإجازة
01/01/2004
مكان الإجازة
جامعة المنصورة - كلية العلوم - Department of Chemistry
الفهرس
Only 14 pages are availabe for public view

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Abstract

­Aluminum phosphate samples containing 5, 10 , 25 and 50 wt% Al2O3 were prepared by mechanical mixing of the appropriate amounts of aluminum phosphate gel and Al(OH)3 gel. chromia­aluminum phosphate samples containing 5, 10, 25 and 50 wt% of Cr2O3 were prepared using the same procedure that behaved for Al2O3/AlPO4 preparation gel. The prepared samples were calcined at 400, 600, 800 and 1000oC for 7 hours. Structural characterization of the catalysts and the phase changes were determined using X­ray technique.Textural parameters, including surface area (SBET), mean pore radius (rH) and total pore volume (Vm) were determined by measuring the adsorption of nitrogen at ­196oC using conventional volumetric apparatus.The surface acidity of All prepared catalysts was estimated using the irreversible adsorption of n­butylamine and applying Langmuir equation. The catalytic conversion of isopropanol over all investigated catalysts was studied. The mechanism of alcohols dehydration was discussed on the basis of bimolecular elimination mechanism.