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Abstract This study aims to comprehensively assess the primordial radioactivity levels and the associated risks due to the manufacturing process of the single super phosphate fertilizers (SSPF) at Kom-Oshim, Fayoum - Egypt. The factory layout, manufacturing process, and production were identified and described. The ambient dose rates were monitored at nine spots in/around the factory premises by two different well-calibrated devices reading in µSv/h. Thirteen samples from different stages were collected from hot spots including ores inputs, storage, and products of phosphate fertilizer (PF) factory. The activity concentrations of radium ( 226 Ra), uranium ( 238 U), thorium ( 232 Th), and potassium ( 40 K) were measured using a gamma-ray spectrometer with a high purity germanium detector. Also, and radiological hazard indices, absorbed gamma dose rate and the corresponding annual effective dose rate and were calculated and compared against the international recommended and permissible limits. Samples selection, preparation, energy and efficiency calibration, MDA, and calculation of the HPGe detector were carried out according to the standard approaches. The activity concentrations of 226 Ra, 238 U, 232 Th and 40 K in the samples varied from 511 ± 45 to 882 ± 65, 500 ± 60 to 919 ± 45, 3.9 ± 0.4 to 8.1 ± 0.3 and 5.4 ± 0.7 to 210 ± 1.9 Bq/kg. Radiation indices for these samples were calculated and found to be higher than the world average values. The ambient dose rates of the factory site were monitored and found to vary from 0.06 to 0.11 (µSv/h). The hazards indices were estimated according to the results of the radioactivity measurements and their levels. It was observed that the calculated values of the air absorbed gamma dose rate (D), annual effective dose (E), radium equivalent (Ra eq ) activity, external and internal hazard index (H in - H ex ) are higher than the world average values and maximum international acceptable limits as reported by UNSCEAR [1]. Based on the results of this study, it can be concluded that the radioactivity concentrations of phosphate fertilizers provide no excess exposure to the inhabitants and it is not suitable to use these materials as building materials for the possible radiation hazard. The ambient dose rate of the factory is found to be radiologically safe for domestic and industrial uses. Finally, the results reported in this study constitute a baseline radioactivity map for major factories in the industry of phosphate fertilizers.Soil samples were characterized by using X-Ray Diffraction (XRD). Keywords: HPGe Gamma assay, Risk and hazard impact assessment, single super Phosphate fertilizers industry. |