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العنوان
Preparation and Evaluation of Oil Sorbent Materials for Treatment of Hydrocarbons Spillage in Fresh Water /
المؤلف
Keshawy, Mohamed Elsayed Hassan.
هيئة الاعداد
باحث / Mohamed Elsayed Hassan Keshawy
مشرف / Ahmed Fawzy El-Kafrawy
مشرف / Thanaa Abd El-Moghny Mohamed
مشرف / Khalid Ismail Kabel
مشرف / Abdul-Raheim Mahmoud Abdul-Raheim
مشرف / Ibrahim H. A. Badr
تاريخ النشر
2016.
عدد الصفحات
210 p. :
اللغة
الإنجليزية
الدرجة
الدكتوراه
التخصص
Organic Chemistry
تاريخ الإجازة
1/1/2016
مكان الإجازة
جامعة عين شمس - كلية العلوم - Chemistry
الفهرس
Only 14 pages are availabe for public view

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from 210

Abstract

The present work include the preparation of new oil sorbents for remediation of environmental pollution caused by petroleum oil spills. This work accomplished by the preparation of a new macromonomer namely, Poly (styrene-co-p-chloromethyl styrene) (PSCMS) by emulsion polymerization method. PSCMS was utilized to react with acrylic acid to produce macromonomer containing polymerizable C=C poly {styrene-co-[4-(methyl acrylate) styrene]} (PSSMA). PSSMA was copolymerized with three kindes of alkyl acrylate monomers, ethylhexyl acrylate (EHA), lauryl methacrylate (LMA), and octadecyl acrylate (ODA) and in the presence of BPO as free radical intiator and two types of crosslinkers divinyl benzene (DVB) and methylene bisacrylamide (MBA) to produce cross-linked copolymers. The cross-linked copolymers were evaluated as oil sorbent using 4 types of organic solvents (DMF, chloroform, toluene and diesel) and then the swelling parameters and swelling kinetics were also calculated.
Key words:
• Hydrocarbon spillage in fresh water by using oil sorbent.
• Emulsion polymerization of styrene with CMS
• Crosslinked copolymers PSSMA / Alkyl acrylate.
• Thermal and morphological properties of the prepared sorbent
• Swelling capacity of sorbent material in different types of organic sorbent.