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العنوان
Study of some physical Properties of proton Conducting Polymer Electrolyte for Fuel Cell Applications /
المؤلف
Gomaa, Mahmoud Mohammed.
هيئة الاعداد
باحث / Mahmoud Mohammed Gomaa
مشرف / Esam E. Abd El-Hady
مشرف / M. Osman
مشرف / Adel Hamed, Azza M. El-Badry
الموضوع
Proton exchange membrane fuel cells. Electrocatalysis. Polyelectrolytes.
تاريخ النشر
2013.
عدد الصفحات
117 P. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الفيزياء والفلك (المتنوعة)
تاريخ الإجازة
1/1/2013
مكان الإجازة
جامعة المنيا - كلية العلوم - Physics
الفهرس
Only 14 pages are availabe for public view

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Abstract

1. Polymer electrolyte membranes (PEMs) for fuel cells, also termed as proton exchange membranes, have been successfully prepared by UV -radiation grafting of styrene onto PET films and consequent selective sulfonation by chlorosulfonic acid.
2. The PEMs displayed excellent thermal, mechanical and electrical properties.
maxImum ion-exchange capacity (lEe) and the proton conductivity of the PEM were measured to be O.7mmol g-l and 58 m Scm respectively.
4. The activation energy was calculated as 6 k jmor1 by Arrhenius plot which reveals that the vehicle mechanism is the predominant conduction mechanism in PETPSSa membranes.
5. PET membranes with D.G ranging from 8 to 166 % have shown free volume hole size (65- 96) A03.The obtained values are found to be lower.