الفهرس | Only 14 pages are availabe for public view |
Abstract 1. Polymer electrolyte membranes (PEMs) for fuel cells, also termed as proton exchange membranes, have been successfully prepared by UV -radiation grafting of styrene onto PET films and consequent selective sulfonation by chlorosulfonic acid. 2. The PEMs displayed excellent thermal, mechanical and electrical properties. maxImum ion-exchange capacity (lEe) and the proton conductivity of the PEM were measured to be O.7mmol g-l and 58 m Scm respectively. 4. The activation energy was calculated as 6 k jmor1 by Arrhenius plot which reveals that the vehicle mechanism is the predominant conduction mechanism in PETPSSa membranes. 5. PET membranes with D.G ranging from 8 to 166 % have shown free volume hole size (65- 96) A03.The obtained values are found to be lower. |