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العنوان
The Use Of Electrocoagulation Technique For The Removal Of Chromium Ions from Industrial Wastewater \
المؤلف
Fata, Aliaa Hussein Mohamed.
هيئة الاعداد
باحث / علياء حسين محمذ فتى
مشرف / محمذ شىوقى محمذ حسن
مشرف / تغريذ محمذ زويل
مناقش / احمد امين زعطوط
مناقش / الفت عبد الشافى فضالى
الموضوع
Chemical Engineering.
تاريخ النشر
2012.
عدد الصفحات
56 p. :
اللغة
الإنجليزية
الدرجة
ماجستير
التخصص
الهندسة (متفرقات)
تاريخ الإجازة
1/1/2012
مكان الإجازة
جامعة الاسكندريه - كلية الهندسة - الهندسة الكيميائية
الفهرس
Only 14 pages are availabe for public view

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Abstract

The prese~t work is concemed with the removal of chromium ions ( Cr+3 & Cr+6) from simulated wastewater by electrocoagulation using an electrolytic cell with vertical cylindrical expanded iron electrodes. Removal efficiency and rate of removal were studied under different c•onditions, which are: I. Electrolysis time:2. Current density.3.Electrolyte (NaCl) concentration.4. Initial chromium ions concentration.5.Initial solution pH .6.Electrode connections. The study revealed the following results: I.As current density increases, % C/3 removal increases, whereas % Cr+6 removal decreases.2.As NaCl concentration increases, % Cr+6 removal increases gradually, while % Cr+3 removal increases up to 1 g/l and decreases beyond this value.3. Maximum Cr+6 removal occurs at pH 4.5, whereas maximum Cr+3 removal occurs at pH 8. 4.As the initial concentration of Cr ions increases, % Cr removal decreases.
5. Monopolar parallel electrode connection is the optimum electrode connection.6.Kinetic study of EC of Cr+6 reveals that the reaction can be described by first order kinetic model. 7.Power consumption evaluation of the present cell design reveals that power consumption increases as current density increases, while it decreases as NaCl concentration increases. 8.Power consumption calculations show that at optimum conditions of Cr+3 removal by EC a 10.98 kV{.h/kg is required whereas at optimum conditions of C/6 removal by EC a 16.14 kW.h/kgis required.9.The difference in the behaviour ofEC of Cr+3 & Cr+6 can be explained in terms of their different removal mechanism.