![]() | Only 14 pages are availabe for public view |
Abstract dimethoxytetrahydrofuran or Lawesson’s reagent ( LR) to give products 35-37, respectively. When compound 2 was allowed to react with hydrazine, ethyl benzoylacetate, acetic anhydride or acetyl chloride or triethylorthoformate gave compounds 38-41, respectively. Compound 3 was reacted with malononitrile, formamide, phenylisocyanate or phenylisothiocyanate to give compounds 42-44, respectively. Also, on treating compound 3 with ethyl cyano-acetate, ethyl benzoylacetate, acetyl chloride or acetic anhydride, hydrazine, 2,5-dimethoxytetrahydrofuran or triethylorthoformate afforded 45-50, respectively. Keywords: 5-amino-3-anilino-1H-pyrazole-4-carbonitrile, 5-amino-1-benzoyl-3-(methylthio)-1H-pyrazole-4-carbonitrile,ethyl 5-amino-1-benzoyl-3-(methylthio)-1H-pyrazole-4-carboxylate, imidazo[1,2-b]pyrazole, pyrazolo[1,5-a]pyrimidines, pyrazolo[3,4-b] |