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Abstract This thesis describes the synthesis of copolymers which can be applied as thin films from organic solutions but which, when exposed to U.V light, degrade to give water soluble fragments. Such polymers have the potential to be used as aqueous developable resists. Free radical copolymerization of methyl vinyl ketone with acrylamide was carried out in dioxane with a range of monomer feed ratios, copolymerizations were stopped below 10% conversion. Reactivity ratios were determined using the Kelen-Tudos method. The copolymers were characterized by N.M.R, I.R, „ G.P.C, and solubility measurements. Solutions of copolymers were photodegraded using U.V light for two, six, twelve, and twenty four hours and the products of degradation were examined by gel permeation chromatography (G.P.C). Films of the copolymers, cast from solution onto glass slides, were exposed to U.V light for 5,15,30,120 minutes, and changes in their solubilities examined. |